روش های کارآمد برای تهیه ترکیبات سیلیکون ۲۰۱۶
Efficient Methods for Preparing Silicon Compounds 2016

1. Cover image

2. Title page

3. Table of Contents

4. Copyright

5. Dedication

6. List of Contributors

7. Preface

1. Arylsilanes as Precursors of Cyclohexa-2,5-dienylsilanes

2. Rhodium-Catalyzed Vinyldiazoesters Insertion Into SiH Bonds. Synthesis of Allylsilanes

3. Lewis Base–Stabilized Silyliums

4. Tetra(silyl)methane, (H3Si)4C, a Volatile Carbosilane for the Chemical Vapor Deposition of Amorphous Silicon Carbide Thin Films

5. Trimethylsilyl Perrhenate—A Nonionic Reagent Soluble in Organic Solvents for the Preparation of Perrhenates

6. Radicals, Anions, and Cations of Silicon and Silylenes

7. Multiple Bonding in Silicon Compounds

8. Silicon-Based Ligands for Transition Metal Coordination

9. Silylenes, Silylaminosilylene, Disilane, Silanimine, Silacyclohexadienones, Bis(silyl)-Alkenes, and Hydrosilanimine

10. Synthesis of Functionalized Silsesquioxanes as Molecular Templates for Hybrid Materials

11. Lithium Tris(2,4,6-triisopropylphenyl)disilenide: A Versatile Reagent for the Transfer of the Disilenyl Group

12. New Phosphine-Stabilized Si(II)-Complexes: Silicon(II)-Hydride and Silacyclopropylidene

13. (Monosodiumoxy)organoalkoxysilanes (Rebrov Salts)—Polyfunctional Monomers for Silicone Syntheses

14. Silicon(II) as a Synthon for the Access of Different Silicon(IV) and Silicon(II) Compounds

15. Silene, Silaimine, and Siletane Derivatives

16. Synthesis of a Zwitterionic 2,4-Disila-1,3-diphosphacyclobutadiene Compound

17. Silanetriols and Aluminosilicates

18. Synthesis of Silicon(II) Compounds and Their Reactions

19. Preparation of the NHC (L1,2) and Its Application for Synthesizing Lewis Base–Stabilized Dichlorosilylene L1,2SiCl2

20. Octaammonium POSS as a Building Block for Constructing Nanohybrid Materials

21. Tungsten- and Ruthenium-Silylene Complexes

22. 1,1-Di-tert-Butylsilacyclopropanes

23. Polysilanes, Polycarbosilanes, Dioxadisilacyclohexane, and Polysiloxanes

24. Synthesis of N-(Silylmethyl)amides of Carboxylic Acids and Related Compounds

25. Carbene Adducts of Silicon(IV) Chlorides: Versatile Reagents for Carbene Transfer and Sources for Cationic Silicon(IV) Complexes

26. Controlling n-Oligosilane Conformation by Stretching on a Staffane Rack

27. Bis-silyl Chelate Ligand Precursor XantsilH2 and Some Ruthenium Xantsil Complexes

28. Silyl(silylene) Complexes of Iron and Ruthenium

29. Cobalt-Methylidyne-Silanetriol as Precursor for Catalytic Hydroformylation in a Two-Phase System

30. Preparation of the SiCS Three- and the SiO2C2 Five-Membered Ring System

31. Preparation of SiF4(NH3)2 and Its Higher Ammoniate SiF4(NH3)2·2NH3

32. Silanols and Silsesquioxanes

33. Hydrido-Silyl Complexes of Chromium With Metal-Hydrogen-Silicon Three-Center Bonds

34. Sol-Gel Processing of Alkoxysilyl-Substituted Metal Complexes

35. Tertiary Alkyl Substituted Octasilsesquioxanes

36. o-(Dimesitylboryl)(dimethylsilyl)benzene: A System of Intramolecular SiH Bond Activation by o-Boryl Group

37. Organosilicon Synthesis for Construction of Organosilicon Clusters

45. Index