سنتز نامتقارن II ۲۰۱۳
Asymmetric Synthesis II 2013

1. Cover

2. Related Titles

3. Title Page

4. Copyright

5. List of Contributors

6. Chapter 1: Catalytic Enantioselective Alkylation of Prochiral Ketone Enolates

7. Chapter 2: Point-to-Planar Chirality Transfer in Total Synthesis: Scalable and Programmable Synthesis of Haouamine A and Its Atropisomer

8. Chapter 3: Tethered Aminohydroxylation

9. Chapter 4: Organocatalyzed Transformations of α, β-Unsaturated Carbonyl Compounds through Iminium Ion Intermediates

10. Chapter 5: The Renaissance of Silicon-Stereogenic Silanes: A Personal Account

11. Chapter 6: Asymmetric Dienamine Activation

12. Chapter 7: Asymmetric Brønsted Acid Catalysis

13. Chapter 8: Quaternary Stereogenic Centers by Enantioselective β-Carbon Eliminations from tert-Cyclobutanols

14. Chapter 9: Total Synthesis of Oseltamivir and ABT-341 Using One-Pot Technology

15. Chapter 10: Enantioselective Annulations with Chiral N-Mesityl N-Heterocyclic Carbenes

16. Chapter 11: Asymmetric Counteranion-Directed Catalysis (ACDC)

17. Chapter 12: Enantioselective Organo-SOMO Catalysis: a Novel Activation Mode for Asymmetric Synthesis

18. Chapter 13: Enantioselective Passerini Reaction

19. Chapter 14: Rapid Enantiomeric Excess Determination

20. Chapter 15: Asymmetric Catalysis of Reversible Reactions

21. Chapter 16: Exploiting Fluorine Conformational Effects in Organocatalyst Design: The Fluorine–Iminium Ion Gauche Effect

22. Chapter 17: Dutch Resolution

23. Chapter 18: Construction of anti-Me-OH Vicinal Relationships in Polyketides

24. Chapter 19: Photoswitchable General Base Catalysts

25. Chapter 20: Asymmetric Halonium Addition to Olefins

26. Chapter 21: Catalytic Asymmetric Gosteli–Claisen Rearrangement (CAGC)

27. Chapter 22: Biomimetic Total Synthesis of the Penifulvin Family

28. Chapter 23: Catalyst-Controlled 1,3-Polyol Syntheses

29. Chapter 24: Enantioselective Carbonyl Allylation and Crotylation from the Alcohol Oxidation Level via C–C Bond Forming Transfer Hydrogenation

30. Chapter 25: Stereoselective Synthesis with Hypervalent Iodine Reagents

31. Chapter 26: Asymmetric Gold-Catalyzed Reactions

32. Chapter 27: Asymmetric Catalysis in the Total Synthesis of Lipids and Polyketides

33. Chapter 28: The Evolving Role of Biocatalysis in Asymmetric Synthesis

34. Chapter 29: Bifunctional Thiourea Catalysts

35. Chapter 30: Catalytic Asymmetric (4 + 3) Cycloadditions Using Allenamides

36. Chapter 31: Application of the Achmatowicz Rearrangement for the Synthesis of Oligosaccharides

37. Chapter 32: Asymmetric C–C Bond Formation Using Chiral Phosphoric Acid

38. Chapter 33: Asymmetric C–H Bond Functionalization

39. Chapter 34: Asymmetric C–C Bond Formation Using Chiral Guanidine Catalysts

40. Chapter 35: Enantioselective Synthesis of Lactones via Rh-Catalyzed Ketone Hydroacylation

41. Chapter 36: Radical Haloalkylation

42. Chapter 37: Asymmetric Hydrovinylation of Alkenes

43. Chapter 38: Heterocycle Construction via Asymmetric Rhodium-Catalyzed Cycloadditions

44. Chapter 39: N-Heterocyclic Carbene-Catalyzed Aldol Desymmetrizations

45. Chapter 40: Strategies for the Asymmetric Total Synthesis of Natural Products: “Chiral Pool” versus Chiral Catalysts

46. Chapter 41: Dynamic Kinetic Asymmetric Transformations Involving Carbon–Carbon Bond Cleavage

47. Chapter 42: Iron-Catalyzed Allylic Substitutions

48. Chapter 43: Asymmetric Conia-Ene Carbocyclizations

49. Chapter 44: Tactics and Strategies in the Total Synthesis of Chlorosulfolipids

50. Chapter 45: Linear Free Energy Relationships (LFERs) in Asymmetric Catalysis

51. Chapter 46: Asymmetric Diamination of Alkenes

52. Chapter 47: Enzymatic Asymmetric Synthesis of Tertiary Alcohols

53. Chapter 48: Oxidative Dearomatization and Organocatalytic Desymmetrization

54. Chapter 49: Total Synthesis of All (–)-Agelastatin Alkaloids

55. Index